Objects of research - the collection of samples of goetite and hematite ores from deposits of Krivoy Rog and Kerch regions. Research methods and apparatus: magnetometry method (magnetometer with Hall sensor), magnetic resonance method (EPR spectrometer RE- 1306 (Russia ), PS100X (Belarus)) , X-ray diffraction (DRON -4M), NGR spectroscopy , X-ray fluorescence analysis. Collections of goetite and hematite ores from deposits of Krivoy Rog and Kerch regions were created.